乙基环丙烷

化合物

乙基环丙烷是一种有机化合物,化学式为C5H10。它可由环丙基乙酮和水合肼反应得到[2],或由乙烯基环丙烷在一种有机钴化合物的光催化下加氢制得。[3]它可以被苯基三氯化钨-三氯化铝分解为1-丁烯乙烯[4]

乙基环丙烷
识别
CAS号 1191-96-4  checkY
PubChem 70933
ChemSpider 64095
性质
化学式 C5H10
摩尔质量 70.13 g·mol−1
熔点 −149.2 °C(124.0 K)[1]
沸点 35.9 °C(309.0 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2023-11-06].
  2. ^ Van Volkenburgh, Ross; Greenlee, K. W.; Derfer, J. M.; Boord, C. E. Synthesis of some cyclopropane hydrocarbons from methyl cyclopropyl ketone. Journal of the American Chemical Society (1949), 71, 172-175
  3. ^ Mendelsohn, Lauren N.; MacNeil, Connor S.; Tian, Lei; Park, Yoonsu; Scholes, Gregory D.; Chirik, Paul J. Visible-Light-Enhanced Cobalt-Catalyzed Hydrogenation: Switchable Catalysis Enabled by Divergence between Thermal and Photochemical Pathways. ACS Catalysis (American Chemical Society (ACS)). 2021-01-13, 11 (3): 1351–1360. ISSN 2155-5435. doi:10.1021/acscatal.0c05136. 
  4. ^ Chandler, Malcolm, Phenyltrichlorotungsten, Chichester, UK: John Wiley & Sons, Ltd, 2001-04-15, doi:10.1002/047084289x.rp141m