五磷唑基五甲基环戊二烯基铁
五磷唑基五甲基环戊二烯基铁是一种金属有机化合物,化学式为C10H15FeP5。它可由五甲基环戊二烯基二羰基铁二聚体和白磷在甲苯中加热反应得到。[2]它也可由五磷化锂、五甲基环戊二烯基锂和氯化亚铁在四氢呋喃中反应得到。[3]它在反应时可视作配体。[4]
五磷唑基五甲基环戊二烯基铁 | |
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别名 | 五磷化五甲基环戊二烯基铁 |
识别 | |
CAS号 | 106211-20-5 ![]() |
SMILES |
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性质 | |
化学式 | C10H15FeP5 |
摩尔质量 | 345.94 g·mol−1 |
熔点 | 193 °C(466 K)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ V. A. Milyukov, E. Hey-Hawkins, O. G. Sinyashin. Reactions of sodium pentaphosphacyclopentadienide with half-sandwich iron complexes. Russian Chemical Bulletin. 2007-03, 56 (3): 549–551 [2020-08-26]. ISSN 1066-5285. doi:10.1007/s11172-007-0089-x (英语).
- ^ Scherer, Otto J.; Brueck, Thomas. [(η5-P5)Fe(η5-C5Me5)], a pentaphosphaferrocene derivative. Angewandte Chemie, 1987. 99 (1): 59.
- ^ Marianne Baudler, Stilianos Akpapoglou, Dimitrios Ouzounis, Fritz Wasgestian, Bernd Meinigke, Herbert Budzikiewicz, Helmut Münster. Zur Kenntnis des Pentaphosphacyclopentadienid-Ions, P5⊖. Angewandte Chemie. 1988-02, 100 (2): 288–289 [2020-08-26]. doi:10.1002/ange.19881000221 (德语).
- ^ Detzel, Michaela; Mohr, Thomas; Scherer, Otto J.; Wolmershaeuser, Gotthelf. [Cp*Fe(η5-P5)], a sandwich complex with various ligand properties. Angewandte Chemie, 106. 10. 1142-1144.
拓展阅读
- Helena Brake, Eugenia Peresypkina, Alexander V. Virovets, Martin Piesch, Werner Kremer, Lisa Zimmermann, Christian Klimas, Manfred Scheer. Iodination of cyclo ‐E 5 ‐Complexes (E=P, As). Angewandte Chemie International Edition. 2020-07-09 [2020-08-26]. ISSN 1433-7851. doi:10.1002/anie.202004812 (英语).