曼陀罗萜二醇

曼陀罗萜二醇(英語:Daturadiol)是一种齐墩果烷型五环三萜化合物,化学式为C30H50O2,存在于曼陀罗D. stramonium[1]毛曼陀罗D. innoxia[2]茄科曼陀罗属Datura)植物和油桐Vernicia fordii[3]等植物中。

曼陀罗萜二醇
IUPAC名
(3S,4aR,5R,6aR,6bS,8aR,12aR,14aR,14bR)-4,4,6a,6b,8a,11,11,14b-Octamethyl-1,2,3,4,4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a,14,14a,14b-icosahydropicene-3,5-diol
识别
CAS号 41498-79-7
PubChem 3084830
ChemSpider 2341835
SMILES
 
  • C[C@@]12CC[C@@]3(C(=CC[C@H]4[C@]3(C[C@H]([C@@H]5[C@@]4(CC[C@@H](C5(C)C)O)C)O)C)[C@@H]1CC(CC2)(C)C)C
ChEBI 138955
KEGG C21821
性质
化学式 C30H50O2
摩尔质量 442.72 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Li J, Lin B, Wang G, Gao H, Qin M. [Chemical constituents of Datura stramonium seeds]. Zhongguo Zhong Yao Za Zhi = Zhongguo Zhongyao Zazhi = China Journal of Chinese Materia Medica. February 2012, 37 (3): 319–22. PMID 22568232 (中文). 
  2. ^ Kocór M, Pyrek JS, Atal CK, Bedi KL, Sharma BR. Triterpenes of Datura innoxia Mill. Structure of daturadiol and daturaolone. The Journal of Organic Chemistry. October 1973, 38 (21): 3685–8. PMID 4745874. doi:10.1021/jo00961a005. 
  3. ^ Pei, Yi-Hua; Kwon, Ok-Kyoung; Lee, Ji-Seon; Cha, Hyuk-Jin; Ahn, Kyung-Seop; Oh, Sei-Ryang; Lee, Hyeong-Kyu; Chin, Young-Won. Triterpenes with Cytotoxicity from the Leaves of Vernicia fordii. Chemical and Pharmaceutical Bulletin. 2013, 61 (6): 674–677. ISSN 0009-2363. PMID 23727783. doi:10.1248/cpb.c13-00055 .