硫代甲亚磺酸-S-甲酯
(重定向自甲基硫代亚磺酸-S-甲酯)
硫代甲亚磺酸-S-甲酯是一种有机硫化合物,化学式为C2H6OS2,或写作CH3S(O)SCH3。它可由二甲基二硫经间氯过氧苯甲酸氧化制得[2],或通过甲亚磺酰氯和甲硫醇在吡啶存在下反应得到。[3]它可以歧化为二甲基二硫和硫代甲磺酸-S-甲酯。[4]
硫代甲亚磺酸-S-甲酯 | |
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英文名 | S-Methyl methanethiosulfinate |
别名 | 甲基硫代亚磺酸-S-甲酯 |
识别 | |
CAS号 | 13882-12-7 ![]() |
性质 | |
化学式 | C2H6OS2 |
摩尔质量 | 110.2 g·mol−1 |
密度 | 1.222 g·cm−3[1] |
沸点 | 64 °C(337 K)(0.5 torr)[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ 1.0 1.1 LaVerne D. Small, John Hays Bailey, Chester J. Cavallito. Alkyl Thiolsulfinates. Journal of the American Chemical Society. 1947-07, 69 (7): 1710–1713 [2022-03-18]. ISSN 0002-7863. doi:10.1021/ja01199a040. (原始内容存档于2022-03-18) (英语).
- ^ Baerbel Bennua-Skalmowski, Helmut Vorbrueggen. Synthesis of a Cyclic 3-Methylsulfonyl Enol Ether. Synthesis. 2015-06-17, 47 (17): 2677–2679 [2022-03-18]. ISSN 0039-7881. doi:10.1055/s-0034-1380217. (原始内容存档于2018-06-05) (英语).
- ^ Peng Qi, Fang Sun, Ning Chen, Hongguang Du. Direct Bis-Alkyl Thiolation for Indoles with Sulfinothioates under Pummerer-Type Conditions. The Journal of Organic Chemistry. 2022-01-21, 87 (2): 1133–1143 [2022-03-18]. ISSN 0022-3263. doi:10.1021/acs.joc.1c02502. (原始内容存档于2022-03-18) (英语).
- ^ Backer, H. J.; Kloosterziel, H. Thiolsulfinic esters. Recueil des Travaux Chimiques des Pays-Bas et de la Belgique, 1954. 73: 129-139. ISSN 0370-7539. CODEN RTCPB4.
参见
- Petra Kučerová, Roman Kubec, Petr Šimek, Lukáš Václavík, Jan Schraml. Allium Discoloration: The Precursor and Formation of the Red Pigment in Giant Onion ( Allium giganteum Regel) and Some Other Subgenus Melanocrommyum Species. Journal of Agricultural and Food Chemistry. 2011-03-09, 59 (5): 1821–1828 [2022-03-18]. ISSN 0021-8561. doi:10.1021/jf104195k. (原始内容存档于2022-03-18) (英语).
- Imen Touihri, Maher Boukhris, Naziha Marrakchi, José Luis, Belgacem Hanchi, Olfa Kallech-Ziri. Chemical Composition and Biological Activities of Allium roseum L. var. grandiflorum Briq. Essential Oil. Journal of Oleo Science. 2015, 64 (8): 869–879 [2022-03-18]. ISSN 1345-8957. doi:10.5650/jos.ess15055. (原始内容存档于2022-03-18) (英语).
- Guodong Zhang, Kirk L. Parkin. A Tissue Homogenate Method To Prepare Gram-Scale Allium Thiosulfinates and Their Disulfide Conjugates with Cysteine and Glutathione. Journal of Agricultural and Food Chemistry. 2013-03-27, 61 (12): 3030–3038 [2022-03-18]. ISSN 0021-8561. doi:10.1021/jf4003818 (英语).