硝酸异丙酯

硝酸异丙酯(英語:Isopropyl nitrate,缩写IPN,或称为硝酸-2-丙醇酯,2-propyl nitrate)是一种有机化合物,分子式C3H7NO3,常温常压下为无色液体,可用作单组元推进剂[5]

Isopropyl nitrate[1]
Skeletal formula of isopropyl nitrate
Ball-and-stick model of the isopropyl nitrate molecule
IUPAC名
Propan-2-yl nitrate
别名 Isopropyl nitrate
Isonite
识别
CAS号 1712-64-7  checkY
PubChem 15575
ChemSpider 14818
SMILES
 
  • CC(C)O[N+](=O)[O-]
InChI
 
  • 1/C3H7NO3/c1-3(2)7-4(5)6/h3H,1-2H3
InChIKey GAPFWGOSHOCNBM-UHFFFAOYAE
性质
化学式 C3H7NO3
摩尔质量 105.09 g/mol g·mol⁻¹
外观 Colorless liquid
密度 1.036 g/cm3, liquid
熔点 -82.5 °C(191 K)
沸点 101.5 °C(375 K)
pKa 16.9[2][3][4]
黏度 0.66 cP at 20 °C
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ A. Abbott. The monopropellant isopropyl nitrate – Its characteristics and uses, and possible future applications. 16th Joint Propulsion Conference. American Institute of Aeronautics and Astronautics. 1980. doi:10.2514/6.1980-1293. 
  2. ^ Reich, Hans. Bordwell pKa table: "Nitroalkanes". University of Wisconsin Chemistry Department. [17 January 2016]. (原始内容存档于9 October 2008). 
  3. ^ Matthews, Walter; et al. Equilibrium acidities of carbon acids. VI. Establishment of an absolute scale of acidities in dimethyl sulfoxide solution. Journal of the American Chemical Society. 1975, 97 (24): 7006. doi:10.1021/ja00857a010. 
  4. ^ Bordwell, F.G. Acidities of carbon acids. VII. Conjugation and strain in some cyclopropyl anions.. Journal of the American Chemical Society. 1975, 97 (24): 7160–7162. doi:10.1021/ja00857a033. 
  5. ^ Shock initiation and detonability of isopropyl nitrate (PDF). [2023-10-30]. (原始内容存档 (PDF)于2022-09-19). 

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