硫氰酸二(吡啶)三苯基膦亚铜

硫氰酸二(吡啶)三苯基膦亚铜是一种配位化合物,化学式为Cu(NCS)(py)2(PPh)3,其中py为吡啶,Ph为苯基。它可由[Cu(NCS)(PPh3)]2(或CuNCSPPh3[1])在热吡啶中结晶得到。[2]

硫氰酸二(吡啶)三苯基膦亚铜
识别
CAS号 1154021-09-6  checkY
SMILES
 
  • S=C=[N-][Cu+]([N]=1C=CC=CC1)([N]=2C=CC=CC2)[P](C=3C=CC=CC3)(C=4C=CC=CC4)C=5C=CC=CC5
性质
化学式 C29H25CuN3PS
摩尔质量 542.11 g·mol−1
外观 浅黄色晶体[1]
熔点 114~120 °C(分解)[2]
溶解性 可溶于氯代溶剂、乙腈和DMSO[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

它可以以单斜晶系P21空间群结晶,晶胞参数a=9.44,b=15.19,c=10.24 Å,β=166.95°。[2]它具有光致发光和摩擦发光特性。[3]

Cu(NCS)(py)2(PPh)3在365 nm激发下的光致发光与黑暗中的摩擦发光(附图)。

参考文献

  1. ^ 1.0 1.1 1.2 Fabio Marchetti, Corrado Di Nicola, Riccardo Pettinari, Ivan Timokhin, and Claudio Pettinari. Synthesis of a Photoluminescent and Triboluminescent Copper(I) Compound: An Experiment for an Advanced Inorganic Chemistry Laboratory. J. Chem. Educ. 2012, 89, 5, 652–655. doi:10.1021/ed2001494
  2. ^ 2.0 2.1 2.2 Claudio Pettinari, Corrado di Nicola, Fabio Marchetti, Riccardo Pettinari, Brian W. Skelton, Neil Somers, Allan H. White, Ward T. Robinson, Michele R. Chierotti, Roberto Gobetto, Carlo Nervi. Synthesis, Characterization, Spectroscopic and Photophysical Properties of New [Cu(NCS){(L-N)2 or (L′-NN)}(PPh3)] Complexes (L-N, L′-NN = Aromatic Nitrogen Base). European Journal of Inorganic Chemistry. 2008. 12. 1974-1984. doi:10.1002/ejic.200701236.
  3. ^ Anıl İncel, Canan Varlikli, Colin D. McMillen, and Mustafa M. Demir. Triboluminescent Electrospun Mats with Blue-Green Emission under Mechanical Force. J. Phys. Chem. C 2017, 121, 21, 11709–11716. doi:10.1021/acs.jpcc.7b02875