苄基叠氮化物

苄基叠氮化物是一种有机叠氮化物,化学式为C7H7N3。它可由卤化苄(如溴化苄)和叠氮化钠的反应制得。[1]它和苯乙炔在石墨炔负载的氧化亚铜的催化下反应,可以得到4-苯基-1-苄基-1,2,3-三唑;[2]而在咪唑铜(II)催化下,得到5-苯基-1-苄基-1,2,3-三唑。[3]

苄基叠氮化物
识别
CAS号 622-79-7  checkY
性质
化学式 C7H7N3
摩尔质量 133.15 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Pengfei Sun; Fang Wei; Chen-Ho Tung; Zhenghu Xu. Copper(I)-catalyzed interrupted click/radical relay: A four-component modular synthesis of triazole sulfones. Chinese Chemical Letters, 2024. 35 (3). doi:10.1016/j.cclet.2023.108478.
  2. ^ Jia Yu; Weiming Chen; Feng He; Weiguo Song; Changyan Cao. Electronic Oxide–Support Strong Interactions in the Graphdiyne-Supported Cuprous Oxide Nanocluster Catalyst. J. Am. Chem. Soc. 2023, 145, 3, 1803–1810. doi:10.1021/jacs.2c10976.
  3. ^ I. Luz , F.X. Llabrés i Xamena, A. Corma. Bridging homogeneous and heterogeneous catalysis with MOFs: “Click” reactions with Cu-MOF catalysts. Journal of Catalysis, 2010. 276 (1). doi:10.1016/j.jcat.2010.09.010.