苊蒽

苊蒽
别名	苯并[d]苊
识别
CAS号	202-03-9
PubChem	107781
SMILES	C=1C=CC2=C(C1)C=C3C=CC=C4C=CC2=C43;
性质
化学式	C16H10
摩尔质量	202.25 g·mol−1
熔点	94-95 °C; 95-96 °C
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

苊蒽^[3]（英語：aceanthrylene）是一种稠环有机化合物，化学式为C₁₆H₁₀。它可以蒽和草酰氯为原料，经多步反应制得。^[2]它可以被肼还原为1,2-二氢苊蒽（維基數據所列：Q27155948）；^[2]或被钠在液氨中还原为2,6-二氢苊蒽。^[4]^[5]它可以和羰基铁^[6]或羰基钌^[4]形成配合物。

参考文献

^ Sangaiah, R.; Gold, A. (1985). A synthesis of aceanthrylene. Organic Preparations and Procedures International, 17 (1), 53–56. doi:10.1080/00304948509355469
^ ^2.0 ^2.1 ^2.2 B. F. Plummer, Z. Y. Al-Saigh, and M. Arfan. Synthesis of aceanthrylene. J. Org. Chem. 1984, 49, 11, 2069–2071. doi:10.1021/jo00185a065.
^ 中国化学会有机化合物命名审定委员会. 有机化合物命名原则 2017. 科学出版社. pp 70. ISBN 978-7-03-055295-2
^ ^4.0 ^4.1 Hideo Nagashima, Akihiro Suzuki, Mitsuharu Nobata, and Kenji Itoh. Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbonyl Cluster as a Template to Control the Hydrogenation Site: First Successful Isolation of 4,5-Dihydroacenaphthylene and 4,5-Dihydroaceanthrylene. J. Am. Chem. Soc. 1996, 118, 3, 687–688. doi:10.1021/ja953742e.
^ Rabideau, Peter W. (2004). The Birch Reduction of Aromatic Compounds. Organic Reactions, 2004. doi:10.1002/0471264180.or042.01
^ Shota Niibayashi, Kouki Matsubara, Masa-aki Haga, and Hideo Nagashima. Thermally Reversible Photochemical Haptotropic Rearrangement of Diiron Carbonyl Complexes Bearing a Bridging Acenaphthylene or Aceanthrylene Ligand. Organometallics 2004, 23, 4, 635–646. doi:10.1021/om034117i.

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[1] Sangaiah, R.; Gold, A. (1985). A synthesis of aceanthrylene. Organic Preparations and Procedures International, 17 (1), 53–56. doi:10.1080/00304948509355469

[Plummer-2] 2.0 ^2.1 ^2.2 B. F. Plummer, Z. Y. Al-Saigh, and M. Arfan. Synthesis of aceanthrylene. J. Org. Chem. 1984, 49, 11, 2069–2071. doi:10.1021/jo00185a065.

[3] 中国化学会有机化合物命名审定委员会. 有机化合物命名原则 2017. 科学出版社. pp 70. ISBN 978-7-03-055295-2

[Hideo-4] 4.0 ^4.1 Hideo Nagashima, Akihiro Suzuki, Mitsuharu Nobata, and Kenji Itoh. Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbonyl Cluster as a Template to Control the Hydrogenation Site: First Successful Isolation of 4,5-Dihydroacenaphthylene and 4,5-Dihydroaceanthrylene. J. Am. Chem. Soc. 1996, 118, 3, 687–688. doi:10.1021/ja953742e.

[5] Rabideau, Peter W. (2004). The Birch Reduction of Aromatic Compounds. Organic Reactions, 2004. doi:10.1002/0471264180.or042.01

[6] Shota Niibayashi, Kouki Matsubara, Masa-aki Haga, and Hideo Nagashima. Thermally Reversible Photochemical Haptotropic Rearrangement of Diiron Carbonyl Complexes Bearing a Bridging Acenaphthylene or Aceanthrylene Ligand. Organometallics 2004, 23, 4, 635–646. doi:10.1021/om034117i.

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