1,4-二氮杂环八硫
1,4-二氮杂环八硫是一种无机化合物，化学式为H2N2S6。它可由氨和二氯化二硫反应制得。[1]它熔化时分解，经四氮化四硫和二氮化四硫分解为硫、氮气和氨气。[2]它在四氢呋喃中可以被乙基锂脱质子，得到S6N2H−和S6N22−。[3]它和乙酸苯汞反应，可以得到不稳定的(C6H5HgN)2S6。[4]
| 1,4-二氮杂环八硫 | |
|---|---|
| |
| 别名 | 1,4-六硫二亚胺 1,4-二亚氨基六硫 1,2,3,4,6,7-六硫杂-5,8-二氮杂环辛烷 |
| 识别 | |
| CAS号 | 1003-76-5 
|
| 性质 | |
| 化学式 | H2N2S6 |
| 摩尔质量 | 222.42 g·mol−1 |
| 外观 | 无色晶体 |
| 熔点 | 133 °C（406 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ 1.0 1.1 H. G. Heal. Isomers of Hexasulphur Diimide. Nature. 1963-07, 199 (4891): 371–371 [2022-12-07]. ISSN 0028-0836. doi:10.1038/199371a0. （原始内容存档于2022-12-07） （英语）.
- ^ Yoshiyuki Kudo, Teruyoshi Kimura, Shuichi Hamada. The Pyrolysis of 1,2,3,4,6,7-Hexathia-5,8-diazocine. Bulletin of the Chemical Society of Japan. 1990-01, 63 (1): 235–240 [2022-12-07]. ISSN 0009-2673. doi:10.1246/bcsj.63.235 （英语）.
- ^ T. Chivers, K. J. Schmidt. Sulphur–nitrogen anions: 14 N and 15 N NMR investigations of the deprotonation of cyclic sulphur imides and sulphur–ammonia solutions. Canadian Journal of Chemistry. 1992-03-01, 70 (3): 710–718 [2022-12-07]. ISSN 0008-4042. doi:10.1139/v92-095 （英语）.
- ^ Robert J. Ramsay, Henry G. Heal, Henri Garcia-Fernandez. Mercury and organomercury drivatives of cyclodiazahexathiane and cycloazaheptathiane: preparation and decomposition. Journal of the Chemical Society, Dalton Transactions. 1976, (3): 234 [2022-12-07]. ISSN 0300-9246. doi:10.1039/dt9760000234 （英语）.
延伸阅读
- Joe Bojes, Tristram Chivers. Sulphur–nitrogen anions: formation from azide ion and elemental sulphur and their role in the synthesis of cyclic sulphur imides. Journal of the Chemical Society, Dalton Transactions. 1975, (16-17): 1715 [2022-12-07]. ISSN 0300-9246. doi:10.1039/dt9750001715 （英语）.