3-溴-2-苯基喹啉
3-溴-2-苯基喹啉是一种有机化合物，化学式为C15H10BrN。它可以苯基溴化镁和3-溴喹啉在四甲基乙二胺存在下反应得到。[1]它和苯乙炔在三乙胺存在下、碘化亚铜和二氯双(三苯基膦)钯催化下反应，可以得到2-苯基-3-苯乙炔基喹啉。[2]
| 3-溴-2-苯基喹啉 | |
|---|---|
| |
| 识别 | |
| CAS号 | 5332-24-1 
|
| 性质 | |
| 化学式 | C15H10BrN |
| 摩尔质量 | 284.15 g·mol−1 |
| 外观 | 浅黄色固体[1] |
| 熔点 | 86 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ 1.0 1.1 1.2 Fang-Fang Zhuo, Wen-Wen Xie, Yong-Xin Yang, Lei Zhang, Pei Wang, Rui Yuan, Chao-Shan Da. TMEDA-Assisted Effective Direct Ortho Arylation of Electron-Deficient N -Heteroarenes with Aromatic Grignard Reagents. The Journal of Organic Chemistry. 2013-04-05, 78 (7): 3243–3249 [2023-03-04]. ISSN 0022-3263. doi:10.1021/jo400152f. （原始内容存档于2023-03-04） （英语）.
- ^ Sophie Janke, Sebastian Boldt, Karapet Ghazargan, Peter Ehlers, Alexander Villinger, Peter Langer. Synthesis of Benzoacridines and Benzophenanthridines by Regioselective Pd-Catalyzed Cross-Coupling Reactions Followed by Acid-Mediated Cycloisomerizations: Synthesis of Benzoacridines and Benzophenanthridines by Regioselective Pd-Catalyzed Cross-Coupling Reactions Followed by Acid-Mediated Cycloisomerizat. European Journal of Organic Chemistry. 2019-09-30, 2019 (36): 6177–6197 [2023-03-04]. doi:10.1002/ejoc.201900913 （英语）.