4-硝基联苯
4-硝基联苯是一种有机化合物，化学式为C
6H
5–C
6H
4NO
2，它是三种硝基联苯的同分异构体之一。它可由联苯的硝化反应制得。[2]它在钯催化下可以被氢气[3]或硼氢化钠[4]还原为4-氨基联苯，或被水合肼还原为N-羟基-4-氨基联苯[5]。
| 4-硝基联苯 | |
|---|---|
| |
| 识别 | |
| CAS号 | 92-93-3 
|
| PubChem | 7114 |
| 性质 | |
| 化学式 | C12H9NO2 |
| 摩尔质量 | 199.21 g·mol−1 |
| 熔点 | 114 °C[1] |
| 沸点 | 340 °C[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ 1.0 1.1 "International Chemical Safety Cards" data were obtained from the National Institute for Occupational Safety and Health (US). Retrieved from SciFinder. [2024-10-09].
- ^ Smith, Keith; Musson, Adam; Deboos, Gareth A. A Novel Method for the Nitration of Simple Aromatic Compounds. The Journal of Organic Chemistry. 1998, 63 (23): 8448–8454. doi:10.1021/jo981557o.
- ^ Jing Li; et al. Pd Nanoparticles in Ionic Liquid Brush: A Highly Active and Reusable Heterogeneous Catalytic Assembly for Solvent-Free or On-Water Hydrogenation of Nitroarene under Mild Conditions. ACS Catal. 2011, 1, 6, 657–664. doi:10.1021/cs200105u.
- ^ Mohammad Gholinejad; et al. Palladium supported on hydrophilic magnetic nanoparticles as a new efficient catalyst in aqueous media. Journal of Molecular Structure, 2023. 1288. 135804. doi:10.1016/j.molstruc.2023.135804.
- ^ Arun K. Shil; Pralay Das. Solid supported platinum(0) nanoparticles catalyzed chemo-selective reduction of nitroarenes to N-arylhydroxylamines. Green Chem., 2013,15, 3421-3428. doi:10.1039/C3GC41179F.