4-硝基聯苯
4-硝基聯苯是一種有機化合物,化學式為C
6H
5–C
6H
4NO
2,它是三種硝基聯苯的同分異構體之一。它可由聯苯的硝化反應製得。[2]它在鈀催化下可以被氫氣[3]或硼氫化鈉[4]還原為4-氨基聯苯,或被水合肼還原為N-羥基-4-氨基聯苯[5]。
4-硝基聯苯 | |
---|---|
識別 | |
CAS號 | 92-93-3 |
PubChem | 7114 |
性質 | |
化學式 | C12H9NO2 |
摩爾質量 | 199.21 g·mol−1 |
熔點 | 114 °C[1] |
沸點 | 340 °C[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
- ^ 1.0 1.1 "International Chemical Safety Cards" data were obtained from the National Institute for Occupational Safety and Health (US). Retrieved from SciFinder. [2024-10-09].
- ^ Smith, Keith; Musson, Adam; Deboos, Gareth A. A Novel Method for the Nitration of Simple Aromatic Compounds. The Journal of Organic Chemistry. 1998, 63 (23): 8448–8454. doi:10.1021/jo981557o.
- ^ Jing Li; et al. Pd Nanoparticles in Ionic Liquid Brush: A Highly Active and Reusable Heterogeneous Catalytic Assembly for Solvent-Free or On-Water Hydrogenation of Nitroarene under Mild Conditions. ACS Catal. 2011, 1, 6, 657–664. doi:10.1021/cs200105u.
- ^ Mohammad Gholinejad; et al. Palladium supported on hydrophilic magnetic nanoparticles as a new efficient catalyst in aqueous media. Journal of Molecular Structure, 2023. 1288. 135804. doi:10.1016/j.molstruc.2023.135804.
- ^ Arun K. Shil; Pralay Das. Solid supported platinum(0) nanoparticles catalyzed chemo-selective reduction of nitroarenes to N-arylhydroxylamines. Green Chem., 2013,15, 3421-3428. doi:10.1039/C3GC41179F.