2,3-丁二胺
2,3-丁二胺(1,2-二甲基乙二胺)是一种有机化合物,化学式为C4H12N2。它可以作为配体和金属形成配合物。[3]
2,3-丁二胺 | |
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别名 | 1,2-二甲基乙二胺 2,3-二氨基丁烷 |
识别 | |
CAS号 | 563-86-0 ![]() 948906-21-6(R,S) ![]() 52165-57-8(R,R) ![]() 52165-56-7(S,S) ![]() 20759-15-3(rel-R,S) ![]() 20699-48-3(±) ![]() |
SMILES |
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性质 | |
化学式 | C4H12N2 |
摩尔质量 | 88.15 g·mol−1 |
沸点 | 44-45 °C(25 mmHg,rac) 46-48 °C(25 mmHg,meso)[1] 55.3-59.3 °C(60 mmHg,DL-threo) 56.1-60.5 °C(60 mmHg,meso)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
合成与反应
参考文献
- ^ Fred Basolo, R. Kent Murmann, and Yun Ti Chen. Dissociation Constants of Substituted Ethylenediamines. J. Am. Chem. Soc. 1953, 75, 6, 1478–1480. doi:10.1021/ja01102a507.
- ^ Robert Ghirardelli and Howard J. Lucas. Stereochemistry of the Opening of the Imine Ring with Ethylamine. J. Am. Chem. Soc. 1957, 79, 3, 734–741. doi:10.1021/ja01560a064.
- ^ Tsuchiya R, Uehara A, Yoshikuni T. Solid-phase thermal cis-trans isomerization of bis(diamine)chromium(III) complexes containing d,l-2,3-butanediamine, d,l-1,2-cyclohexanediamine, or d,l-2,4-pentanediamine. Inorganic Chemistry, 1982, 21(2): 590-594. doi:10.1021/ic00132a025.
- ^ Harold Kohn and Sang Hun Jung. New stereoselective method for the preparation of vicinal diamines from olefins and cyanamide. Journal of the American Chemical Society 1983 105 (12), 4106-4108. doi:10.1021/ja00350a068.
- ^ T. S. Zhivotova; G. A. Abdulina; G. G. Baikenova; A. M. Gazaliev; Z. K. Aitpaeva (2006). Synthesis and antimicrobial activity of potassium salts of alkylene-N,N′ bis(dithiocarbamic) acids. Pharmaceutical Chemistry Journal, 40 (8), 416–417. doi:10.1007/s11094-006-0142-3