2-(二苯基膦基)苯甲醚
化合物
2-(二苯基膦基)苯甲醚是一种有机磷化合物,化学式为(C6H5)2P(C6H4-2-OCH3)。它是白色固体,可溶于有机溶剂。它在金属有机化学和均相催化领域可用作配体。它是一种典型的介稳(hemilabile)配体。[3]
2-(二苯基膦基)苯甲醚 | |
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IUPAC名 (2-Methoxyphenyl)(diphenyl)phosphine | |
识别 | |
CAS号 | 53111-20-9 ![]() |
PubChem | 603401 |
ChemSpider | 524530 |
SMILES |
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性质 | |
化学式 | C19H17OP |
摩尔质量 | 292.31 g·mol−1 |
外观 | 白色固体 |
密度 | 1.188 g/cm3[1] |
熔点 | 123 °C(396 K)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ Suomalainen, Pekka; Jääskeläinen, Sirpa; Haukka, Matti; Laitinen, Riitta H.; Pursiainen, Jouni; Pakkanen, Tapani A. Structural and Theoretical Studies ofortho-Substituted Triphenylphosphane Ligands and Their Rhodium(I) Complexes. European Journal of Inorganic Chemistry. 2000, 2000 (12): 2607–2613. doi:10.1002/1099-0682(200012)2000:12<2607::AID-EJIC2607>3.0.CO;2-R.
- ^ Dayaker, Gandrath; Chevallier, Floris; Gros, Philippe C.; Mongin, Florence. Deprotonative metalation of substituted aromatics using mixed lithium–cobalt combinations. Tetrahedron. 2010, 66 (46): 8904–8910. ISSN 0040-4020. doi:10.1016/j.tet.2010.09.053.
- ^ Jeffrey, J. C.; Rauchfuss, T. B. Metal complexes of hemilabile ligands. Reactivity and structure of dichlorobis(o-(diphenylphosphino)anisole)ruthenium(II). Inorganic Chemistry. 1979, 18 (10): 2658. doi:10.1021/ic50200a004.