2-(二苯基膦基)苯甲醚

化合物

2-(二苯基膦基)苯甲醚是一種有機磷化合物,化學式為(C6H5)2P(C6H4-2-OCH3)。它是白色固體,可溶於有機溶劑。它在金屬有機化學均相催化領域可用作配體。它是一種典型的介穩(hemilabile)配體。[3]

2-(二苯基膦基)苯甲醚
IUPAC名
(2-Methoxyphenyl)(diphenyl)phosphine
識別
CAS號 53111-20-9  checkY
PubChem 603401
ChemSpider 524530
SMILES
 
  • COc1ccccc1P(c2ccccc2)c3ccccc3
性質
化學式 C19H17OP
摩爾質量 292.31 g·mol−1
外觀 白色固體
密度 1.188 g/cm3[1]
熔點 123 °C(396 K)[2]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ Suomalainen, Pekka; Jääskeläinen, Sirpa; Haukka, Matti; Laitinen, Riitta H.; Pursiainen, Jouni; Pakkanen, Tapani A. Structural and Theoretical Studies ofortho-Substituted Triphenylphosphane Ligands and Their Rhodium(I) Complexes. European Journal of Inorganic Chemistry. 2000, 2000 (12): 2607–2613. doi:10.1002/1099-0682(200012)2000:12<2607::AID-EJIC2607>3.0.CO;2-R. 
  2. ^ Dayaker, Gandrath; Chevallier, Floris; Gros, Philippe C.; Mongin, Florence. Deprotonative metalation of substituted aromatics using mixed lithium–cobalt combinations. Tetrahedron. 2010, 66 (46): 8904–8910. ISSN 0040-4020. doi:10.1016/j.tet.2010.09.053. 
  3. ^ Jeffrey, J. C.; Rauchfuss, T. B. Metal complexes of hemilabile ligands. Reactivity and structure of dichlorobis(o-(diphenylphosphino)anisole)ruthenium(II). Inorganic Chemistry. 1979, 18 (10): 2658. doi:10.1021/ic50200a004.