二乙基乙酰胺
化合物
二乙基乙酰胺是一種有機化合物，化學式為C6H13NO。它可由二乙胺和乙酸酐[3]或N-乙酰氧基丁二酰亞胺[4]反應製得。在催化劑的存在下，它可以被氫氣還原為三乙胺。[5]
| 二乙基乙酰胺 | |
|---|---|
| |
| 識別 | |
| CAS號 | 685-91-6 
|
| 性質 | |
| 化學式 | C6H13NO |
| 摩爾質量 | 115.17 g·mol⁻¹ |
| 密度 | 0.9130 g·cm−3[1] |
| 熔點 | ＜20 °C[2] |
| 沸點 | 185.5 °C[2] |
| 若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。 | |
參考文獻
- ^ Kormer, M. V.; Tolchinskii, S. E.; Maretina, I. A. Vinylacetylenic ynamines as dehydrating reagents. Zhurnal Organicheskoi Khimii, 1983. 19 (6): 1166-1170. ISSN: 0514-7492.
- ^ 2.0 2.1 "Hazardous Substances Data Bank" data were obtained from the National Library of Medicine (US). Retrieved from SciFinder. [2021-05-17].
- ^ Gangadhar Meshram, Vishvanath D. Patil. Simple and Efficient Method for Acetylation of Alcohols, Phenols, Amines, and Thiols Using Anhydrous NiCl 2 Under Solvent-Free Conditions. Synthetic Communications. 2009-11-18, 39 (24): 4384–4395 [2021-05-17]. ISSN 0039-7911. doi:10.1080/00397910902906529 （英語）.
- ^ Hong Li, Zi-Bo Pang, Zhi-Feng Jiao, Fei Lin. Synthesis and Application of a Microgel-Supported Acylating Reagent by Coupled Ring-Opening Metathesis Polymerization and Activators Re-Generated by Electron Transfer for Atom Transfer Radical Polymerization. Journal of Combinatorial Chemistry. 2010-03-08, 12 (2): 255–259 [2021-05-17]. ISSN 1520-4766. doi:10.1021/cc900162w （英語）.
- ^ Mario Stein, Bernhard Breit. Catalytic Hydrogenation of Amides to Amines under Mild Conditions. Angewandte Chemie International Edition. 2013-02-18, 52 (8): 2231–2234 [2021-05-17]. doi:10.1002/anie.201207803 （英語）.