四氯環氧乙烷

化合物

四氯環氧乙烷是一種有機化合物,化學式為C2Cl4O,它是四氯乙烯的可能的代謝產物。[3]它是穩定的化合物,但是加熱可以重排為三氯乙酰氯[4]

四氯環氧乙烷
IUPAC名
tetrachlorooxirane
別名 Perchloroethylene oxide (PCEO), Epoxyperchlorovinyl, Tetrachloroepoxyethane
識別
CAS號 16650-10-5  checkY
PubChem 27973
ChemSpider 26022
SMILES
 
  • ClC1(Cl)C(Cl)(Cl)O1
性質
化學式 C2Cl4O
摩爾質量 181.83 g·mol−1
外觀 liquid
密度 1.72 g/cm3[1]
熔點 –58 °C[2]
沸點 110 °C [1]
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

它可以代謝為三氯乙酰氯,並水解為三氯乙酸[5]

參考文獻

  1. ^ 1.0 1.1 Yaws, C. L. (2015). The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals: Physical Properties for More Than 54,000 Organic and Inorganic Chemical Compounds, Coverage for C1 to C100 Organics and Ac to Zr Inorganics.
  2. ^ Notes - Preparation and Properties of Tetrachloroethylene Oxide Donald Frankel, Claude Johnson, and Harold Pitt The Journal of Organic Chemistry 1957 22 (9), 1119-1120 DOI: 10.1021/jo01360a614
  3. ^ Raat, W. K. d. (2003). 133 Tetrachloroethylene (PER). Sweden: Arbetslivsinstitutet.
  4. ^ R. W. Campbell & O. Vogl (1977) A Practical Synthesis of Tetrachloroethylene Oxide, Journal of Macromolecular Science: Part A - Chemistry, 11:3, 515-534, DOI: 10.1080/00222337708061286
  5. ^ Testa, B., Mayer, J. M. (2003). Hydrolysis in Drug and Prodrug Metabolism. page 633