甲酸鎘
化合物
甲酸鎘是鎘的甲酸鹽,化學式為Cd(HCOO)2,它可由碳酸鎘和甲酸水溶液反應得到。它在210 °C開始分解,熱分解的中間產物是碳酸鎘,最終生成氧化鎘,惰性氣氛中還能檢測到金屬鎘。[1]
甲酸鎘 | ||
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識別 | ||
CAS號 | 4464-23-7 | |
SMILES |
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性質 | ||
化學式 | Cd(HCOO)2 | |
摩爾質量 | 202.45 g·mol⁻¹ | |
外觀 | 白色固體 | |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
- ^ Barbara Małecka, Agnieszka Łącz. Thermal decomposition of cadmium formate in inert and oxidative atmosphere. Thermochimica Acta. 2008-12, 479 (1-2): 12–16 [2021-03-17]. doi:10.1016/j.tca.2008.09.003. (原始內容存檔於2018-06-26) (英語).
- ^ Kharitonova, R. I.; Kharitonov, Yu. Ya. Reaction of crystalline cadmium carboxylates with piperidine. Koordinatsionnaya Khimiya, 1975. 1 (7): 916-919. ISSN: 0132-344X.
- ^ Czakis-Sulikowska, D.; Radwanska-Doczekalska, J.; Markiewicz, M. Synthesis and characterization of new dn metal complexes with 4,4'-bipyridine and formates. Polish Journal of Chemistry, 2003. 77 (10). 1255-1261. ISSN: 0137-5083.
- ^ M. Stoev, S. Ruseva, B. Keremidchieva. Preparation of CdS by thermal decomposition of double salts and saturated solutions of the systems Cd(HCOO)2-CS(NH2)2-CH3OH and Cd(CH3COO)2-CS(NH2)2-CH3OH. Monatshefte für Chemie / Chemical Monthly. 1994-11, 125 (11): 1215–1221 [2021-03-17]. ISSN 0026-9247. doi:10.1007/BF00813807 (英語).
- ^ Vladimir N. Krasil』nikov, Tatyana V. Dyachkova, Alexander P. Tyutyunnik, Olga I. Gyrdasova, Yuliya A. Perevozchikova, Vyacheslav V. Marchenkov, Harald W. Weber. Precursor synthesis and magnetic properties of Cd 1−x Fe x O (0 ⩽ x ⩽ 0.07). Mendeleev Communications. 2017-09, 27 (5): 456–458 [2021-03-17]. doi:10.1016/j.mencom.2017.09.008. (原始內容存檔於2018-06-10) (英語).