2-硝基溴苯
化合物
2-硝基溴苯是一種有機化合物,化學式為C6H4BrNO2。它可以在溴苯的硝化反應中生成,但並非主產物。[3][4]2-硝基苯胺的重氮化-溴化反應[5]以及2-溴苯胺的氧化反應[6]可以以較高產率得到2-硝基溴苯。
2-硝基溴苯 | |
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識別 | |
CAS號 | 577-19-5 |
SMILES |
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性質 | |
化學式 | C6H4BrNO2 |
摩爾質量 | 202.01 g·mol⁻¹ |
熔點 | 41—42 °C(314—315 K)[1] |
沸點 | 258—265 °C(531—538 K)[2] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
- ^ Robert A. Benkeser, Philip E. Brumfield. Nitration of Organosilicon Compounds with Copper Nitrate. Journal of the American Chemical Society. 1951-10, 73 (10): 4770–4773 [2021-05-19]. ISSN 0002-7863. doi:10.1021/ja01154a087 (英語).
- ^ Inagaki, Sigenobu. Diphenylisatin and its derivatives. IV. Monobromo derivatives of dianisoleisatin and its oxidation product. Yakugaku Zasshi, 1938. 58: 961-975. ISSN: 0031-6903.
- ^ Radoslaw R Bak, Andrew J Smallridge. A fast and mild method for the nitration of aromatic rings. Tetrahedron Letters. 2001-09, 42 (38): 6767–6769 [2021-05-19]. doi:10.1016/S0040-4039(01)01378-8. (原始內容存檔於2020-11-06) (英語).
- ^ Christopher G Frost, Joseph P Hartley, David Griffin. Counterion effects in indium-catalysed aromatic electrophilic substitution reactions. Tetrahedron Letters. 2002-07, 43 (27): 4789–4791 [2021-05-19]. doi:10.1016/S0040-4039(02)00931-0. (原始內容存檔於2018-07-01) (英語).
- ^ Woonphil Baik, Wanqiang Luan, Hyun Joo Lee, Cheol Hun Yoon, Sangho Koo, Byeong Hyo Kim. Efficient one-pot transformation of aminoarenes to haloarenes using halodimethylisulfonium halides generated in situ. Canadian Journal of Chemistry. 2005-03-01, 83 (3): 213–219 [2021-05-19]. ISSN 0008-4042. doi:10.1139/v05-026 (英語).
- ^ Jia Liu, Jue Li, Jiangmeng Ren, Bu-Bing Zeng. Oxidation of aromatic amines into nitroarenes with m-CPBA. Tetrahedron Letters. 2014-02, 55 (9): 1581–1584 [2021-05-19]. doi:10.1016/j.tetlet.2014.01.073. (原始內容存檔於2018-06-10) (英語).