一氧化四磷
一氧化四磷是一种无机化合物,化学式为P4O。结构为P4(=O)的物质曾被认为是白磷在空气中氧化的产物之一[1],但红外光谱未能观测到这一物种的存在,只分辨出了P2O、OPOPO、O2PPO2、PO2、PO2−和PO3−等物种。[2]
一氧化四磷 | |||
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识别 | |||
CAS号 | 114584-25-7 127666-31-3(环状) | ||
性质 | |||
化学式 | P4O | ||
摩尔质量 | 139.89 g·mol⁻¹ | ||
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
- ^ F. S. Dainton, H. M. Kimberley. The reaction between phosphorus vapour and oxygen. Transactions of the Faraday Society. 1950, 46: 629 [2021-06-07]. ISSN 0014-7672. doi:10.1039/tf9504600629 (英语).
- ^ Charles W. Bauschlicher, Mingfei Zhou, Lester Andrews. A Study of the Products of the Reaction of Phosphorus and Dioxygen †. The Journal of Physical Chemistry A. 2000-04, 104 (16): 3566–3571 [2021-06-07]. ISSN 1089-5639. doi:10.1021/jp993623b. (原始内容存档于2020-12-10) (英语).
- ^ Matthew McCluskey, Lester Andrews. Matrix infrared spectra of the products of the phosphorus (P2) and ozone reaction. The Journal of Physical Chemistry. 1991-04, 95 (8): 2988–2994 [2021-06-07]. ISSN 0022-3654. doi:10.1021/j100161a011 (英语).
拓展阅读
- David Leonard Chapman, F. Austin Lidbury. XCIV.—Non-existence of the so-called suboxide of phosphorus. J. Chem. Soc., Trans. 1899, 75 (0): 973–978 [2021-06-07]. ISSN 0368-1645. doi:10.1039/CT8997500973 (英语).