1-苯乙炔基金刚烷

1-苯乙炔基金刚烷是一种有机化合物,化学式为C18H20。它可由1-氟金刚烷法语1-Fluoroadamantane和(三甲基硅基乙炔基)苯在三(五氟苯基)铝催化下反应制得。[1]它和1,2-二氯苯中反应,可以得到1-金刚烷基苯基二硫杂环丁烯。[2]

1-苯乙炔基金刚烷
别名 1-金刚烷基-2-苯基乙炔
识别
CAS号 74203-39-7  checkY
PubChem 144631
SMILES
 
  • C(#CC12CC3CC(CC(C3)C1)C2)C=4C=CC=CC4
性质
化学式 C18H20
摩尔质量 236.35 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ Jaiswal, Amit K.; Goh, Kelvin K. K.; Sung, Simon; Young, Rowan D. Aluminum-Catalyzed Cross-Coupling of Silylalkynes with Aliphatic C–F Bonds. Organic Letters (American Chemical Society (ACS)). 2017-03-28, 19 (7): 1934–1937. ISSN 1523-7060. doi:10.1021/acs.orglett.7b00712. 
  2. ^ Choi, Keun Soo; Akiyama, Isao; Hoshino, Masamatsu; Nakayama, Juzo. A Convenient Synthesis of 1,2-Dithietes and 1,2-Dithioxo Compounds Stabilized by Buttressing and Resonance Effects, Respectively, by Sulfuration of Alkynes with Elemental Sulfur. Bulletin of the Chemical Society of Japan (The Chemical Society of Japan). 1993, 66 (2): 623–629. ISSN 0009-2673. doi:10.1246/bcsj.66.623.