三硫代硼酸三苯酯

三硫代硼酸三苯酯是一种有机化合物,化学式为C18H15BS3。它可以苯硫酚三氯化硼为原料反应制得。[2]它和环戊烯-3-酮反应,可以得到1,3-二苯硫基环戊烯。[3]它和HNi(dmpe)2反应,可以得到三乙胺苯硫基硼烷。[4]

三硫代硼酸三苯酯
识别
CAS号 1041-16-3  checkY
性质
化学式 C18H15BS3
摩尔质量 338.32 g·mol−1
熔点 57 °C[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ J. C. Lockhart. 229. Mechanism of substitution at a boron atom. Part I. Journal of the Chemical Society (Resumed). 1962: 1197 [2022-03-19]. ISSN 0368-1769. doi:10.1039/jr9620001197 (英语). 
  2. ^ Michael T. Mock, Robert G. Potter, Donald M. Camaioni, Jun Li, William G. Dougherty, W. Scott Kassel, Brendan Twamley, Daniel L. DuBois. Thermodynamic Studies and Hydride Transfer Reactions from a Rhodium Complex to BX 3 Compounds. Journal of the American Chemical Society. 2009-10-14, 131 (40): 14454–14465 [2022-03-19]. ISSN 0002-7863. doi:10.1021/ja905287q. (原始内容存档于2022-03-19) (英语). 
  3. ^ Theodore Cohen, David A. Bennett, Albert J. Mura. Preparative methods for .beta.-acyl vinyl anion equivalents from enones or allyl sulfides. The Journal of Organic Chemistry. 1976-07, 41 (14): 2506–2507 [2022-03-19]. ISSN 0022-3263. doi:10.1021/jo00876a041. (原始内容存档于2022-03-19) (英语). 
  4. ^ Michael T. Mock, Robert G. Potter, Molly J. O’Hagan, Donald M. Camaioni, William G. Dougherty, W. Scott Kassel, Daniel L. DuBois. Synthesis and Hydride Transfer Reactions of Cobalt and Nickel Hydride Complexes to BX3 Compounds. Inorganic Chemistry. 2011-12-05, 50 (23): 11914–11928 [2022-03-19]. ISSN 0020-1669. doi:10.1021/ic200857x.