五氯环丙烷
化合物
五氯环丙烷是一种有机化合物，化学式为C
3HCl
5。它是无色液体，具有淡薄荷味。[1]它在100 °C以上不稳定，会异构化为1,1,3,3,3-五氯丙烯。[3]它可由三氯乙烯和二氯卡宾在碱存在下加成得到。[4]它和氢氧化钾反应，得到四氯环丙烯。[5]
| 五氯环丙烷 | |
|---|---|
| |
| IUPAC名 1,1,2,2,3-Pentachlorocyclopropane | |
| 识别 | |
| CAS号 | 6262-51-7 |
| PubChem | 22631 |
| SMILES |
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| 性质 | |
| 化学式 | C3HCl5 |
| 摩尔质量 | 214.31 g·mol−1 |
| 外观 | 无色液体 |
| 气味 | Mild, minty[1] |
| 密度 | 1.668 g/cm3[2] |
| 沸点 | 56 °C[1] |
| 折光度n D |
1.51[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ 1.0 1.1 1.2 Pentachlorocyclopropane Stephen W. Tobey and Robert West The University of Wisconsin (1965)
- ^ 2.0 2.1 Yaws, C. L. (2015). The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals: Physical Properties for More Than 54,000 Organic and Inorganic Chemical Compounds, Coverage for C1 to C100 Organics and Ac to Zr Inorganics.
- ^ Organic Reaction Mechanisms 1966: An Annual Survey Covering the Literature Dated December 1965 Through November 1966. Page 228
- ^ Strain and Its Implications in Organic Chemistry: Organic Stress and Reactivity. (2012). Page 384
- ^ Advances in Alicyclic Chemistry. (2013). Elsevier Science. page 57