姜黄烯

化合物

姜黄烯是一种红没药烷型倍半萜,首次从郁金根茎精油中发现[1],化学式C15H22,可见于马缨丹[2]蜘蛛香[3]短舌匹菊[4]以及[1]等植物的精油中。其有R型和S型两种构型,(S)-(+)-姜黄烯为郁金根茎精油的成分,也是一些珊瑚的气味物质。(R)-(-)-姜黄烯对烟草粉虱粉虱有驱赶效果[1]

姜黄烯
英文名 curcumene
识别
CAS号 644-30-4
PubChem 92139
ChemSpider 83185
SMILES
 
  • CC1=CC=C(C=C1)C(C)CCC=C(C)C
InChI
 
  • InChI=1S/C15H22/c1-12(2)6-5-7-14(4)15-10-8-13(3)9-11-15/h6,8-11,14H,5,7H2,1-4H3
InChIKey VMYXUZSZMNBRCN-UHFFFAOYSA-N
ChEBI 62757
性质
化学式 C15H22
摩尔质量 202.34 g·mol−1
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考资料

  1. ^ 1.0 1.1 1.2 Sansinenea, Estibaliz; Cabrera Vivas, Blanca M.; Ortiz, Aurelio. A Natural Curcumene Bisabolane Sesquiterpene: Syntheses and Recent Applications. Current Organic Synthesis. 2015, 12 (4): 431-439. 
  2. ^ Peter Weyerstahl; Helga Marschall; Alexander Eckhardt; Christian Christiansen. Constituents of commercial Brazilian lantana oil. Flavour and Fragrance Journal. 2002-08, 14 (1). doi:10.1002/(SICI)1099-1026(199901/02)14:1<15::AID-FFJ777>3.0.CO;2-M. 
  3. ^ Rein Bos; Herman J. Woerdenbag; Henk Hendriks; H. Friso Smit; Håkan V. Wikström. Composition of the Essential Oil from Roots and Rhizomes ofValeriana wallichii DC.. Flavour and Fragrance Journal. 2002-08, 12 (2). doi:10.1002/(SICI)1099-1026(199703)12:2<123::AID-FFJ613>3.0.CO;2-4. 
  4. ^ H. Hendriks; R. Bos; H. J. Woerdenbag. The Essential Oil ofTanacetum parthenium (L.) Schultz-Bip.. Flavour and Fragrance Journal. 1996-11, 11 (6). doi:10.1002/(SICI)1099-1026(199611)11:6<367::AID-FFJ598>3.0.CO;2-R.