一碲化鐿
化合物
一碲化鐿是一種無機化合物,為鐿的碲化物之一,化學式YbTe。它可由碲化鐿(Yb2Te3)的高溫還原反應製得,[1]或氯化鐿、碲和氫氣反應得到:[2]
一碲化鐿 | |
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識別 | |
CAS號 | 12125-58-5 ![]() |
性質 | |
化學式 | TeYb |
摩爾質量 | 300.64 g·mol−1 |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
- YbCl3 + H2 → YbCl2 + 2 HCl
- YbCl2 + H2 + Te → YbTe + 2 HCl
[(py)2Yb(μ-η2-η2-PhNNPh)(TePh)]2·2py的熱分解也會生成一碲化鐿,但同時會產生氮化鐿。[3]
參考文獻
- ^ Senff, Heinz; Klemm, Wilhelm. Measurements on bivalent and quadrivalent compounds of the rare earths. IX. The selenides and tellurides of bivalent ytterbium. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1939. 242: 92-96.
- ^ Obolonchik, V. A.; Yanaki, A. A. Synthesis of some rare-earth metal tellurides. Khal'kogenidy, 1970. 2: 141-148. CODEN D8MMYC.
- ^ Anna Kornienko, Deborah Freedman, Thomas J. Emge, John G. Brennan. Heteroleptic Lanthanide Compounds with Chalcogenolate Ligands: Reduction of PhNNPh/PhEEPh (E = Se or Te) Mixtures with Ln (Ln = Ho, Er, Tm, Yb). Thermolysis Can Give LnN or LnE. Inorganic Chemistry. 2001-01-01, 40 (1): 140–145 [2023-06-13]. ISSN 0020-1669. doi:10.1021/ic000499y. (原始內容存檔於2023-05-10) (英語).
拓展閱讀
- Ziya S. Aliev, Gulnara I. Ibadova, Jean-Claude Tedenac, Mahammad B. Babanly. Study of the YbTe–SnTe–Sb2Te3 quasi-ternary system. Journal of Alloys and Compounds. 2014-07, 602: 248–254 [2023-06-13]. doi:10.1016/j.jallcom.2014.03.036. (原始內容存檔於2018-06-09) (英語).
- Martin Siron, Oxana Andriuc, Kristin A. Persson. Data-Driven Investigation of Tellurium-Containing Semiconductors for CO 2 Reduction: Trends in Adsorption and Scaling Relations. The Journal of Physical Chemistry C. 2022-08-11, 126 (31): 13224–13236 [2023-06-13]. ISSN 1932-7447. doi:10.1021/acs.jpcc.2c04810. (原始內容存檔於2023-05-16) (英語).