二高氯酸氧釩

二高氯酸氧釩也稱高氯酸釩(IV)醯,是一種無機化合物,化學式為VO(ClO4)2。它可由V(OH)4和3.5 N高氯酸反應得到。[1]它的五水合物可溶於水,在水中解離為[VO(H2O)5]2+和ClO4[2]它可以和甲基苯基亞碸英語Methyl phenyl sulfoxide形成配合物VO(ClO4)2·4MPSO。[3]它可用於製備其它VO2+化合物。[4]

二高氯酸氧釩
識別
CAS號 15305-73-4(無水)  checkY
15333-33-2(五水)  checkY
SMILES
 
  • O=[V+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
性質
化學式 VO(ClO4)2
溶解性 可溶
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

參考文獻

  1. ^ Tishchenko, A. F.; Golub, A. M. Formation of vanadium(IV) perchlorate. Izvestiya Vysshikh Uchebnykh Zavedenii, Khimiya i Khimicheskaya Tekhnologiya, 1974. 17 (5): 656-658. ISSN: 0579-2991.
  2. ^ Sathyanarayana, D. N.; Patel, C. C. A physicochemical study of vanadyl perchlorate pentahydrate. Indian Journal of Chemistry, 1965. 3 (11): 486-489. ISSN: 0019-5103.
  3. ^ Agarwal, R. K.; Singh, Pitam; Singh, Lakshman. Synthesis and characterization of oxovanadium(IV) complexes of methyl phenyl sulfoxide. Revue Roumaine de Chimie, 1993. 38 (7): 853-858. ISSN: 0035-3930.
  4. ^ Agarwal, Ram K.; Singh, Lakshman; Sharma, Deepak K.; Singh, Ritu. Synthesis, spectral and thermal investigations of some oxovanadium(IV) complexes of hydrazones of isonicotinic acid hydrazide. Turkish Journal of Chemistry, 2005. 29 (3). 309-316. ISSN: 1300-0527.