檸檬烯-1,2-環氧化物

化合物

檸檬烯-1,2-環氧化物是一種環氧化物,化學式為C10H16O,它存在於一些柑橘屬的植物中。[1]

檸檬烯-1,2-環氧化物
別名 檸檬烯氧化物
識別
CAS號 1195-92-2  checkY
SMILES
 
  • O1C2CC(C(=C)C)CCC12C
性質
化學式 C10H16O
摩爾質量 152.23 g·mol−1
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。

合成及反應

檸檬烯-1,2-環氧化物可由檸檬烯過氧化氫反應製得。[2]它可以被汞齊還原為檸檬烯。[3]它可以在檸檬烯-1,2-環氧化物水解酶英語Limonene-1,2-epoxide hydrolase催化下水解:[4]

 

參考文獻

  1. ^ Kun Zhang, Ying Lin, Zhou-Jian Diao, Wei-Hua Zhang, Sui-Ping Zheng, Shu-Li Liang, Shuang-Yan Han. Enzymatic Process Enhances the Flavour Profile and Increases the Proportion of Esters in Citrus Essential Oils. Chemistry & Biodiversity. 2017. 14 (11): e1700187. doi:10.1002/cbdv.201700187.
  2. ^ Satoshi Sakaguchi; Yutaka Nishiyama; Yasutaka Ishii. Selective Oxidation of Monoterpenes with Hydrogen Peroxide Catalyzed by Peroxotungstophosphate (PCWP). J. Org. Chem. 1996, 61, 16, 5307–5311. doi:10.1021/jo960275q.
  3. ^ Peter W. D. Mitchell. Deoxygenation of epoxides with aluminum. Organic Preparations and Procedures International, 1990. 22 (4). doi:10.1080/00304949009356321.
  4. ^ Armstrong RN, Cassidy CS. New structural and chemical insight into the catalytic mechanism of epoxide hydrolases. Drug Metabolism Reviews. 2000-01-01, 32 (3–4): 327–338. PMID 11139132. S2CID 27172869. doi:10.1081/DMR-100102337.