4-乙基叔丁苯
4-乙基叔丁苯是一種有機化合物,化學式為C12H18,它可由4-叔丁基苯乙烯在鈀(或納米鎳[2])催化下加氫得到。[3]在乙酸亞銅的催化下,它和三甲基氰矽烷、N-氟代二(苯磺醯)胺反應,苄位氫氰化,得到(αS)-α-甲基-4-叔丁基苯乙腈。[4]它和氟硼酸硝醯在乙腈中反應,可以得到3-硝基-4-乙基叔丁苯。[5]
4-乙基叔丁苯 | |
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別名 | 對乙基叔丁苯 4-叔丁基乙苯 |
識別 | |
CAS號 | 7364-19-4 ![]() |
性質 | |
化學式 | C12H18 |
摩爾質量 | 162.27 g·mol−1 |
密度 | 0.8641 g·cm−3(20 °C)[1] |
熔點 | −38.35 °C(234.80 K)[1] |
沸點 | 212.1 °C(485.2 K)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
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- ^ Wen Zhang, Fei Wang, Scott D. McCann, Dinghai Wang, Pinhong Chen, Shannon S. Stahl, Guosheng Liu. Enantioselective cyanation of benzylic C–H bonds via copper-catalyzed radical relay. Science. 2016-09-02 [2021-12-24]. PMC 5488708 . PMID 27701109. doi:10.1126/science.aaf7783 (英語).
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