叠氮化四苯基𬭸
叠氮化四苯基𬭸是一种有机磷化合物，化学式为(C6H5)4PN3。它可由四苯基氯化鏻和叠氮化钠反应制得，或四苯基溴化鏻或四苯基碘化鏻和叠氮化银反应得到。[1]它可用于一些叠氮配合物的合成。[2][3]
| 叠氮化四苯基𬭸 | |
|---|---|
| |
| 别名 | 四苯基叠氮化𬭸 |
| 识别 | |
| CAS号 | 79180-81-7 
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| 性质 | |
| 化学式 | C24H20N3P |
| 摩尔质量 | 381.41 g·mol−1 |
| 密度 | 1.283 g/cm3（110 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
参考文献
- ^ 1.0 1.1 Haiges, Ralf; Schroer, Thorsten; Yousufuddin, Muhammed; Christe, Karl O. The Syntheses and Structures of Ph4EN3 (E = P, As, Sb), an Example for the Transition from Ionic to Covalent Azides within the Same Main Group. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2005, 631 (13-14): 2691–2695. ISSN 0044-2313. doi:10.1002/zaac.200500289.
- ^ Haiges, Ralf; Boatz, Jerry A.; Vij, Ashwani; Vij, Vandana; Gerken, Michael; Schneider, Stefan; Schroer, Thorsten; Yousufuddin, Muhammed; Christe, Karl O. Polyazide Chemistry: Preparation and Characterization of As(N3)5, Sb(N3)5, and [P(C6H5)4][Sb(N3)6]. Angewandte Chemie International Edition (Wiley). 2004-12-09, 43 (48): 6676–6680. ISSN 1433-7851. doi:10.1002/anie.200461730.
- ^ Schulz, Axel; Villinger, Alexander. Binary Polyazides of Cadmium and Mercury. Chemistry – A European Journal (Wiley). 2015-01-22, 21 (9): 3649–3663. ISSN 0947-6539. doi:10.1002/chem.201406023.