叠氮化四苯基𬭸

叠氮化四苯基𬭸是一种有机磷化合物,化学式为(C6H5)4PN3。它可由四苯基氯化鏻叠氮化钠反应制得,或四苯基溴化鏻或四苯基碘化鏻和叠氮化银反应得到。[1]它可用于一些叠氮配合物的合成。[2][3]

叠氮化四苯基𬭸
别名 四苯基叠氮化𬭸
识别
CAS号 79180-81-7  checkY
性质
化学式 C24H20N3P
摩尔质量 381.41 g·mol−1
密度 1.283 g/cm3(110 K)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

  1. ^ 1.0 1.1 Haiges, Ralf; Schroer, Thorsten; Yousufuddin, Muhammed; Christe, Karl O. The Syntheses and Structures of Ph4EN3 (E = P, As, Sb), an Example for the Transition from Ionic to Covalent Azides within the Same Main Group. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2005, 631 (13-14): 2691–2695. ISSN 0044-2313. doi:10.1002/zaac.200500289. 
  2. ^ Haiges, Ralf; Boatz, Jerry A.; Vij, Ashwani; Vij, Vandana; Gerken, Michael; Schneider, Stefan; Schroer, Thorsten; Yousufuddin, Muhammed; Christe, Karl O. Polyazide Chemistry: Preparation and Characterization of As(N3)5, Sb(N3)5, and [P(C6H5)4][Sb(N3)6]. Angewandte Chemie International Edition (Wiley). 2004-12-09, 43 (48): 6676–6680. ISSN 1433-7851. doi:10.1002/anie.200461730. 
  3. ^ Schulz, Axel; Villinger, Alexander. Binary Polyazides of Cadmium and Mercury. Chemistry – A European Journal (Wiley). 2015-01-22, 21 (9): 3649–3663. ISSN 0947-6539. doi:10.1002/chem.201406023.