镁钛矿
镁钛矿是一种镁钛氧化物矿物,化学式为MgTiO3。为钛铁矿族的成员。晶体属于三方晶系,通常不透明,颜色呈黑色至红黑色。
镁钛矿 | |
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基本资料 | |
类别 | 氧化物矿物 |
化学式 | MgTiO3 |
IMA记号 | Gk[1] |
施特龙茨分类 | 4.CB.05 |
戴纳矿物分类 | 4.3.5.2 |
晶体分类 | 三方锥体 (3) (H-M记号相同) |
晶体空间群 | R3 |
晶胞 | a = 5.05478(26) Å c = 13.8992(7) Å; Z = 6 |
性质 | |
分子量 | 120.17 g·mol−1 |
颜色 | 黑色、少见的红宝石红色;红色内反射 |
晶体惯态 | 管状棱柱状晶体,也作为细小的颗粒状团块 |
晶系 | 三方晶系 |
解理 | {1011}良好解理 |
莫氏硬度 | 5 - 6 |
光泽 | 亚金属光泽 |
条痕 | 紫褐色 |
透明性 | 不透明至半透明 |
比重 | 3.79 - 4.2 |
密度 | 3.79 - 4.2 g/cm3 (测量值) 3.895 g/cm3 (计算值)g/cm³ |
光学性质 | 单轴(-) |
折射率 | nω = 2.310 - 2.350 nε = 1.950 - 1.980 |
双折射 | δ = 0.360 - 0.370 |
多色性 | 弱, O = 偏粉红的红色,E = 偏褐色到偏紫色的红色 |
参考文献 | [2][3][4] |
它于 1892 年首次被描述[5] ,出现在锡兰宝石砾石砂矿中。它以苏格兰地质学家阿奇博尔德·盖基爵士(Archibald Geikie,1835-1924 年)的名字命名。 它出现在变质的不纯镁灰岩、源自超镁铁岩的蛇纹岩、金伯利岩和碳酸岩中。伴生矿物包括金红石、尖晶石、斜辉石、钙钛矿、透辉石、蛇纹石、镁橄榄石、水镁石、水滑石、绿泥石和方解石。
参见
参考资料
- ^ Warr, L.N. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 2021, 85 (3): 291–320. Bibcode:2021MinM...85..291W. S2CID 235729616. doi:10.1180/mgm.2021.43 .
- ^ Handbook of Mineralogy (PDF). [2023-08-04]. (原始内容存档 (PDF)于2010-07-14).
- ^ Geikielite on Mindat.org. [2023-08-04]. (原始内容存档于2023-06-26).
- ^ Geikielite on Webmineral. [2023-08-04]. (原始内容存档于2023-06-10).
- ^ Fletcher, L. Geikielite and Baddeleyite, Two New Mineral Species. Nature. 1892, 46 (1200): 620–621. Bibcode:1892Natur..46..620F. doi:10.1038/046620b0 .
延伸阅读
- Ghiorso, Mark S. Thermodynamic properties of hematite — Ilmenite — Geikielite solid solutions. Contributions to Mineralogy and Petrology. 1990, 104 (6): 645–667. Bibcode:1990CoMP..104..645G. S2CID 98522254. doi:10.1007/BF01167285.
- Reynard, B.; Guyot, F. High-temperature properties of geikielite (MgTiO3-ilmenite) from high-temperature high-pressure Raman spectroscopy ? Some implications for MgSiO3-ilmenite. Physics and Chemistry of Minerals. 1994, 21 (7): 441. Bibcode:1994PCM....21..441R. S2CID 96095190. doi:10.1007/BF00202274.
- Baura-Peña, M. P.; Martínez-Lope, M. J.; García-Clavel, M. E. Synthesis of the mineral geikielite MgTiO3. Journal of Materials Science. 1991, 26 (16): 4341. Bibcode:1991JMatS..26.4341B. S2CID 94170430. doi:10.1007/BF00543648.
- Robie, Richard A.; Haselton, H.T.; Hemingway, Bruce S. Heat capacities and entropies at 298.15 K of MgTiO3(geikielite), ZnO (zincite), and ZnCO3 (smithsonite). The Journal of Chemical Thermodynamics. 1989, 21 (7): 743 [2023-08-04]. doi:10.1016/0021-9614(89)90058-X. (原始内容存档于2023-08-04).
- Gieré, Reto. Titanian clinohumite and geikielite in marbles from the Bergell contact aureole. Contributions to Mineralogy and Petrology. 1987, 96 (4): 496–502 [2023-08-04]. Bibcode:1987CoMP...96..496G. S2CID 86861792. doi:10.1007/BF01166694. (原始内容存档于2023-08-04).
- Parthasarathy, G. Electrical resistivity of nano-crystalline and natural MgTiO3−geikielite at high-pressures up to 8 GPa. Materials Letters. 2007, 61 (21): 4329–4331. doi:10.1016/j.matlet.2007.01.097.
- Mitchell, Jeremy N.; Yu, Ning; Sickafus, Kurt E.; Nastasi, Michael A.; McClellan, Kenneth J. Ion irradiation damage in geikielite (MgTiO3). Philosophical Magazine A. 1998, 78 (3): 713. Bibcode:1998PMagA..78..713M. doi:10.1080/01418619808241931.
- Chao, G. Y.; Hounslow, A. W. Geikielite; a new Canadian occurrence. The Canadian Mineralogist. June 1967, 9 (1): 95–100 [2023-08-04]. (原始内容存档于2016-08-18).