4-溴苯胺
4-溴苯胺是一种有机化合物，化学式为C6H6BrN。它可由4-硝基溴苯的还原反应制得。[2]它和苯硼酸在碱和催化剂的存在下反应，可以得到4-氨基联苯。[3]它和乙酸酐反应，得到4-乙酰氨基溴苯。[4]
| 4-溴苯胺[1] | |||
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| IUPAC名 4-Bromoaniline | |||
| 别名 | 对溴苯胺 4-氨基溴苯 | ||
| 识别 | |||
| CAS号 | 106-40-1 
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| PubChem | 7807 | ||
| ChemSpider | 7519 | ||
| SMILES |
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| InChI |
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| InChIKey | WDFQBORIUYODSI-UHFFFAOYAG | ||
| UN编号 | 2811 | ||
| EINECS | 203-393-9 | ||
| RTECS | BW9280000 | ||
| 性质 | |||
| 化学式 | C6H6BrN | ||
| 摩尔质量 | 172.02 g mol−1 g·mol⁻¹ | ||
| 密度 | 1.5 g/cm3 | ||
| 熔点 | 60—64 °C（333—337 K） | ||
| 溶解性（水） | <0.1 g/100 mL at 23 °C | ||
| 磁化率 | -84.06·10−6 cm3/mol | ||
| 危险性 | |||
GHS危险性符号  
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| GHS提示词 | Danger | ||
| H-术语 | H302, H311, H315, H319, H332, H335, H373 | ||
| P-术语 | P260, P261, P264, P270, P271, P280, P301+312, P302+352, P304+312, P304+340, P305+351+338, P312, P314, P321 | ||
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |||
参考文献
- ^ 4-Bromoaniline （页面存档备份，存于互联网档案馆）, Chemblink.com
- ^ Dong-Fang Hou, Zhi-Feng Jiao, Zai-Peng Liang, Yun-Wei Wang, Xiao-Ning Guo, Xiang-Yun Guo. Selectivity control of Pt/SiC catalysts for photothermocatalytic hydrogenation of 3-nitrostyrene. Applied Surface Science. 2020-10, 526: 146616 [2021-06-26]. doi:10.1016/j.apsusc.2020.146616 （英语）.
- ^ Babak Karimi, Mina Tavakolian, Fariborz Mansouri, Hojatollah Vali. Nanopalladium on Magnetic Ionic Nanoparticle Network (MINN) as an Efficient and Recyclable Catalyst with High Ionic Density and Dispersibility. ACS Sustainable Chemistry & Engineering. 2019-02-18, 7 (4): 3811–3823 [2021-06-26]. ISSN 2168-0485. doi:10.1021/acssuschemeng.8b04566. （原始内容存档于2021-01-25） （英语）.
- ^ Yang Gao, Yuanyou Mao, Biwei Zhang, Yingying Zhan, Yanping Huo. Regioselective nitration of anilines with Fe(NO 3 ) 3 ·9H 2 O as a promoter and a nitro source. Organic & Biomolecular Chemistry. 2018, 16 (21): 3881–3884 [2021-06-26]. ISSN 1477-0520. doi:10.1039/C8OB00841H （英语）.