4-溴苯胺
4-溴苯胺是一種有機化合物,化學式為C6H6BrN。它可由4-硝基溴苯的還原反應製得。[2]它和苯硼酸在鹼和催化劑的存在下反應,可以得到4-氨基聯苯。[3]它和乙酸酐反應,得到4-乙酰氨基溴苯。[4]
4-溴苯胺[1] | |||
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IUPAC名 4-Bromoaniline | |||
別名 | 對溴苯胺 4-氨基溴苯 | ||
識別 | |||
CAS號 | 106-40-1 | ||
PubChem | 7807 | ||
ChemSpider | 7519 | ||
SMILES |
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InChI |
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InChIKey | WDFQBORIUYODSI-UHFFFAOYAG | ||
UN編號 | 2811 | ||
EINECS | 203-393-9 | ||
RTECS | BW9280000 | ||
性質 | |||
化學式 | C6H6BrN | ||
摩爾質量 | 172.02 g mol−1 g·mol⁻¹ | ||
密度 | 1.5 g/cm3 | ||
熔點 | 60—64 °C(333—337 K) | ||
溶解性(水) | <0.1 g/100 mL at 23 °C | ||
磁化率 | -84.06·10−6 cm3/mol | ||
危險性 | |||
GHS危險性符號 | |||
GHS提示詞 | Danger | ||
H-術語 | H302, H311, H315, H319, H332, H335, H373 | ||
P-術語 | P260, P261, P264, P270, P271, P280, P301+312, P302+352, P304+312, P304+340, P305+351+338, P312, P314, P321 | ||
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
- ^ 4-Bromoaniline (頁面存檔備份,存於網際網路檔案館), Chemblink.com
- ^ Dong-Fang Hou, Zhi-Feng Jiao, Zai-Peng Liang, Yun-Wei Wang, Xiao-Ning Guo, Xiang-Yun Guo. Selectivity control of Pt/SiC catalysts for photothermocatalytic hydrogenation of 3-nitrostyrene. Applied Surface Science. 2020-10, 526: 146616 [2021-06-26]. doi:10.1016/j.apsusc.2020.146616 (英語).
- ^ Babak Karimi, Mina Tavakolian, Fariborz Mansouri, Hojatollah Vali. Nanopalladium on Magnetic Ionic Nanoparticle Network (MINN) as an Efficient and Recyclable Catalyst with High Ionic Density and Dispersibility. ACS Sustainable Chemistry & Engineering. 2019-02-18, 7 (4): 3811–3823 [2021-06-26]. ISSN 2168-0485. doi:10.1021/acssuschemeng.8b04566. (原始內容存檔於2021-01-25) (英語).
- ^ Yang Gao, Yuanyou Mao, Biwei Zhang, Yingying Zhan, Yanping Huo. Regioselective nitration of anilines with Fe(NO 3 ) 3 ·9H 2 O as a promoter and a nitro source. Organic & Biomolecular Chemistry. 2018, 16 (21): 3881–3884 [2021-06-26]. ISSN 1477-0520. doi:10.1039/C8OB00841H (英語).